液体導入用ホルダー
ハミングバード・サイエンティフィック社の液体導入用ホルダーは、流動液体や静止液体中の試料を、原子レベルの分解能で可視化することができます。このシステムは、オールインワンの完全ソリューションであり、材料特性評価に新たな道を切り開きます。
この画期的な製品は、2010年にSmall Business Innovation ResearchのTibbets賞（写真）、2011年にFederal Lab Consortium賞を受賞しています。The Microanalysis Society of Americaは、特許を取得したハミングバードの液体導入用ホルダーを使用して行われた、史上初のその場液中電気化学による研究に対し、2011年Birks賞を授与しています。
受賞した液中電気化学用ホルダーは、TEM内部で液中電気化学実験を可能にした世界初の商用ホルダーです。
連続フロー
当社の液体導入用ホルダーは、独自の液体セル・アセンブリと安全機能により、コンタミネーションやダメージから顕微鏡を保護します。交換可能なチップと、ユーザーによる交換可能なチューブにより、クロス・コンタミネーションのない実験を行うための新しい機能を組み込んだシ ス テ ム へ と 、簡 単 に ア ッ プ グ レ ー ド す る こ と が で き ま す 。
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デュアルフロー
当社の本ホルダー用デュアルフロー・ミキシングチップは、1つの環境セル内で2つの液体を混合することが可能です。本設計では、同速、または異速での液体双方の利用が可能です。試薬の混合だけでなく、従来のシングルフロー用としても、研究に利用することができます。
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静止流体セル
当社では静止流体実験用のホルダーも提供しています。試料はホルダーチップ内のマイクロ流路セル内に封入され、特許取得済みの密封機構によりTEMの真空域から隔離されます。このチップは、ハミングバード・サイエンティフィックの幅広い液体セルチップ構成と組み合わせることができ、それぞれが特定の実験要件に対応するよう設計されています。連続フローおよびデュアルフロー構成は、実験の柔軟性を最大限に高めたい研究者のために、静止流体実 験もサ ポートして います。
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電気化学
ハミングバード・サイエンティフィックは、TEM内部で行われる液中電気化学実験に対応するホルダーを市販した始めての企業です。その後、ホルダー機能の改良を続け、さまざまな材質の電気化学チップに接続可能なバイアス・コンタクトを内蔵することで、より高度な電気化学研究を可能にしています。特に、電池材料に関する重要な研究に使用されています。
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加熱システム
当社の液体加熱システムは、特に、中温度域で試料を均質加熱するために最適化されています。液体セル中に内包された薄膜ヒーターによって溶液の沸点まで加熱することができます。
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分光測定
ハミングバードの液体導入用ホルダーは、液体セル内の分光測定用にエネルギー分散型X線分光器（EDS）機能を搭載しています。当社の特殊なチップは、液体層を可能な限り薄くし、液体セル内での電子エネルギー損失分光法（EELS）を可能にします。これにより、高倍率での元素分析、およびマッピングを直接行うことができます。EDS液体セルホルダーの大きな視野角は、試料からEDS検出器への直接アクセスが可能です。（複数の検出器構成でも可能）
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相互相関
本ホルダーは、ホルダー先端部の着脱により、液体中の試料の透過電子顕微鏡、走査電子顕微鏡、X線顕微鏡、光学顕微鏡のマルチモード相関イメージングを可能にします。各手法に対応した専用ホルダーを用意しており、すべてのホルダーは、同じ液体セルチップと互換利用することができ、マルチモード相関イメージングを可能にします。
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水蒸気供給
ハミングバード・サイエンティフィックの低圧蒸気システムは、当社の流体導入用ホルダーの試料チャンバーに水蒸気を導入することで、その場反応条件の制御性を高め、デリケートな生体試料を保護することができます。このシステムは、ハミングバードの液体および気体ホルダーにアドオンすることができ、既存のすべての環境セ ル・シ ス テム に 使 用 することが で きま す。
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TEMの安全性
当社の高真空ポンプステーションは、TEM試料台用の真空保存とシールチェックを一体化したコンパクトな機構です。排気時間が短く、ベース圧が低い（10-6mbar）、ホルダー先端部にはガラス製の覗き窓があるのが特徴です。
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形状と力によって導かれる自己組織化
シンガポール国立大学の科学者たちは、ハミングバードのリキッドセルTEMイメージング・プラットフォームを用いて、ナノ粒子の形状が、自己組織化と成長に影響を与えることを実証しました。これらの結果はAdvanced Materials誌に掲載されています。この研究では、単層の親和性界面活性剤を処理した棒状、二角錐、球状、立方体など異なる形状のナノ粒子を密閉した液体セル内へ流しました。ナノ粒子ダイナミクスの直接観察から、ナノ粒子の相互作用の強さはその形状に依存することがわかりました。例えば、立方体の金ナノ粒子は、方向性を持った（面と面を合わせた）付着が見られます。この研究は、自己組織化によってボトムアップ的に新材料を開発するための大きな一歩となり得ます。
参考文献: Utkur Mirsaidov et al. Shape-Dependent Hydrophobic Forcesによって導かれるナノ粒子相互作用。 アドバンストマテリアルズ (2018). Abstract
Edit
Interaction mechanism of NPs with different shapes. Image copyright © 2018 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim
| 1400 Series | |
| Number of Inlets | 1 or 2 depending on model, single outlet |
| Biasing Contacts | 4 |
| Tubing Type | User-replaceable microfluidic tubing |
| Delivery System | Variable speed liquid delivery system |
| Tip Type | Removable tip |
| Flow Type | Continuous flow or static liquid |
| EDS Compatible | Yes |
| TEM Compatibility | TFS/FEI, JEOL, Hitachi, Zeiss |
システム構成機器
- 液体導入用ホルダー
- ホルダースタンド
- ホルダー先端カバー
- マイクロ流路用シリンジポンプ
- 高真空ポンプ
- 顕微鏡一体型シールチェック・ステーション
- アクセサリキットとリキッドセルスターターバッチ、その他のアクセサリー（付随品）や特殊チップは別途お求めいただけます。
- オプションの薄膜ヒーターコントローラー電源
- オプションの生物学的ポテンショスタット
| Wenhui Wang, Hongwei Yan, Utkarsh Anand, and Utkur Mirsaidov. “Visualizing the Conversion of Metal–Organic Framework Nanoparticles into Hollow Layered Double Hydroxide Nanocages,” JACS (2021) | Abstract |
| See Wee Chee, Thomas Lunkenbein Lunkenbein, Robert Schlög, and Beatriz Roldan Cuenya. “In situ and operando electron microscopy in heterogeneous catalysis – Insights into multi-scale chemical dynamics,” Journal of Physics: Condensed Matter (2021) | Abstract |
| Albert Grau-Carbonell, Sina Sadighikia, Tom A. J. Welling, Relinde J. A. van Dijk-Moes, Ramakrishna Kotni, Maarten Bransen, Alfons van Blaaderen*, and Marijn A. van Huis. “In Situ Study of the Wet Chemical Etching of SiO2 and Nanoparticle@SiO2 Core–Shell Nanospheres,” ACS Applied Nano Materials (2021) | Abstract |
| Aram Yoon, Antonia Herzog, Philipp Grosse, Daan Hein Alsem, See Wee Chee, and Beatriz Roldán Cuenya. “Dynamic Imaging of Nanostructures in an Electrolyte with a Scanning Electron Microscope,” Microscopy and Microanalysis (2021) | Abstract |
| David A. Shapiro, Sergey Babin, Richard S. Celestre, Weilun Chao, Raymond P. Conley, Peter Denes, Bjoern Enders, Pablo Enfedaque, Susan James, John M. Joseph, Harinarayan Krishnan, Stefano Marchesini, Krishna Muriki, Kasra Nowrouzi, Sharon R. Oh, Howard Padmore, Tony Warwick, Lee Yang, Valeriy V. Yashchuk, Young-Sang Yu and Jiangtao Zhao. “An ultrahigh-resolution soft x-ray microscope for quantitative analysis of chemically heterogeneous nanomaterials,” Science Advances (2020) | Abstract |
| Wenhui Wang, Hongwei Yan, Utkarsh Anand, and Utkur Mirsaidov. “Visualizing the Conversion of Metal–Organic Framework Nanoparticles into Hollow Layered Double Hydroxide Nanocages,” JACS (2020) | Abstract |
| Haifeng Wang, Xiaoqin Zhou, Yunhui Huang, Xin Chen, and Chuanhong Jin. “Interactions of sub-five-nanometer diameter colloidal palladium nanoparticles in solution investigated via liquid cell transmission electron microscopy,” RSC Advances (2020) | Abstract |
| Philipp Grosse, Aram Yoon, Clara Rettenmaier, See Wee Chee, and Beatriz Roldan Cuenya. “Growth Dynamics and Processes Governing the Stability of Electrodeposited Size-Controlled Cubic Cu Catalysts,” The Journal of Physical Chemistry C (2020) | Abstract |
| Sina Sadighikia, Albert Grau‐Carbonell, Tom A.J. Welling, Ramakrishna Kotni, Fabian Hagemans, Arnout Imhof, Marijn A. van Huis, and Alfons van Blaaderen. “Low‐dose liquid cell electron microscopy investigation of the complex etching mechanism of rod‐shaped silica colloids,” nano select (2020) | Abstract |
| Mario Alberto Gomez, Ruonan Jiang, Miao Song, Dongsheng Li, Alan Scott Lea, Xu Ma, Haibo Wang, Xiuling Yin, Shaofeng Wang, and Yongfeng Jia. ” Further insights into the Fe(ii) reduction of 2-line ferrihydrite: a semi in situ and in situ TEM study,” Nanoscale Advances (2020) | Abstract |
| Lili Liu, Duo Song, Biao Jin, Michael A. Sinnwell, Jun Liu, James J. De Yoreo, and Maria L. Sushko. “Role of the Solvent–Surfactant Duality of Ionic Liquids in Directing Two-Dimensional Particle Assembly,” The Journal of Physical Chemistry C (2020) | Abstract |
| Tzu-Hsien Shen, Liam Spillane, Jan Vavra, Thi Ha My Pham, Jiayu Peng, Yang Shao-Horn, and Vasiliki Tileli. “Oxygen Evolution Reaction in Ba0.5Sr0.5Co0.8Fe0.2O3-δ Aided by Intrinsic Co/Fe Spinel-Like Surface,” JACS (2020) | Abstract |
| Muhua Sun, Ying Li, Bo Zhang, Christos Argyropoulos, Peter Sutter, and Eli Sutter. “Plasmonic Effects on the Growth of Ag Nanocrystals in Solution,” Langmuir (2020) | Abstract |
| Mei Sun, Bocheng Yu, Mengyu Hong, Zhiwei Li, Fengjiao Lyu, Xing Li, Zhihong Li, Xianlong Wei, Zheng Zhang, Yue Zhang, and Qing Chen. “Controlling the Facet of ZnO during Wet Chemical Etching Its (000 1⎯⎯ ) O‐Terminated Surface,” Small (2020) | Abstract |
| Pan Liu, Pan Liu, Qing Chen, Yoshikazu Ito, Jiuhui Han, Shufen Chu, Xiaodong Wang, Kolan Madhav Reddy, Shuangxi Song, Akihiko Hirata, and Mingwei Chen. “Dealloying Kinetics of AgAu Nanoparticles by In Situ Liquid-Cell Scanning Transmission Electron Microscopy,” Nano Letters (2020) | Abstract |
| Quintin Cheek, Eli Fahrenkrug, Sofiya Hlynchuk, Daan Hein Alsem, Norman J. Salmon, and Stephen Maldonado. “In Situ Transmission Electron Microscopy Measurements of Ge Nanowire Synthesis with Liquid Metal Nanodroplets in Water,” ACS Nano (2020) | Abstract |
| Lili Liu, Elias Nakouzi, Maria L. Sushko, Gregory K. Schenter, Christopher J. Mundy, Jaehun Chun, and James J. De Yoreo. “Connecting energetics to dynamics in particle growth by oriented attachment using real-time observations,” Nature Communications (2020) | Abstract |
| Zhaoming Liu, Zhisen Zhang, Zheming Wang, Biao Jin, Dongsheng Li, Jinhui Tao, Ruikang Tang, and James J. De Yoreo. “Shape-preserving amorphous-to-crystalline transformation of CaCO3 revealed by in situ TEM,” PNAS (2020) | Abstract |
| Mi Yoo, Young-Sang Yu, Hyunwoo Ha, Siwon Lee, Jin-Seok Choi, Sunyoung Oh, Eunji Kang, Hyuk Choi, Hyesung An, Kug-Seung Lee, Jeong Young Park, Richard Celestre, Matthew A. Marcus, Kasra Nowrouzi, Doug Taube, David A. Shapiro, WooChul Jung, Chunjoong Kim, and Hyun You Kim. ” A tailored oxide interface creates dense Pt single-atom catalysts with high catalytic activity,” Energy & Environmental Science (2020) | Abstract |
| Zhaoming Liu, Changyu Shao, Biao Jin, Zhisen Zhang, Yueqi Zhao, Xurong Xu, and Ruikang Tang. “Crosslinking ionic oligomers as conformable precursors to calcium carbonate,” Nature (2019) | Abstract |
| Chen Hou, Jiuhui Han, Pan Liu, Chuchu Yang, Gang Huang, Takeshi Fujita, Akihiko Hirata, and Mingwei Chen. “Operando Observations of SEI Film Evolution by Mass‐Sensitive Scanning Transmission Electron Microscopy,” Advanced Energy Materials (2019) | Abstract |
| Noah Glachman, Noah Geller, Alexander Shea, V. Antoine Verret, Khim Karki, Julio Rodriquez-Manzo, Norman J. Salmon, Daan Hein Alsem, Deep Jariwala, and Eric Stach. “Development of a Method to Characterize Active Sites in Photocatalysis using operando Transmission Electron Microscopy,” Microscopy and Microanalysis (2019) | Abstract |
| Tyler Mefford, Khim Karki, Daan Hein Alsem, David Shapiro, Norman Salmon, and William C. Chueh. “Operando Scanning Transmission X-ray Microscopy of Co(OH)2 Oxygen Evolution Electrocatalysts,” Microscopy and Microanalysis (2019) | Abstract |
| Biao Jin, Yanming Wang, Zhaoming Liu, Arthur France‐Lanord, Jeffrey C. Grossman, Chuanhong Jin, and Ruikang Tang. “Revealing the Cluster‐Cloud and Its Role in Nanocrystallization,” Advanced Materials (2019) | Abstract |
| Shu Fen Tan, See Wee Chee, Zhaslan Baraissov, Hongmei Jin, Teck Leong Tan and Utkur Mirsaidov. “Intermediate Structures of Pt–Ni Nanoparticles during Selective Chemical and Electrochemical Etching,” The Journal of Physical Chemistry Letters (2019) | Abstract |
| Shih-Ting Wang, Yiyang Lin, Michael H. Nielsen, Cheng Yu Song, Michael R. Thomas, Christopher D. Spicer, Roland Kröger, Peter Ercius, Shaul Alonic and Molly M. Stevens. “Shape-controlled synthesis and in situ characterisation of anisotropic Au nanomaterials using liquid cell transmission electron microscopy,” Nanoscale (2019) | Abstract |
| See Wee Chee, Utkarsh Anand, Geeta Bisht, Shu Fen Tan, and Utkur Mirsaidov. “Direct Observations of the Rotation and Translation of Anisotropic Nanoparticles Adsorbed at a Liquid–Solid Interface,” Nano Letters (2019) | Abstract |
| Yingying Jiang, Xiao Li, Xiaoming Ma, Haifeng Wang, Hui Zhang, Zheng Liu, Ze Zhang and Chuanhong Jin. “Spherical to truncated octahedral shape transformation of palladium nanocrystals driven by e-beam in aqueous solution,” Nano Research (2019) | Abstract |
| Wan-Gil Jung, Jeung Hun Park, Yong-Ryun Jo and Bong-Joong Kim. “Growth Kinetics of Individual Au Spiky Nanoparticles Using Liquid-Cell Transmission Electron Microscopy,” The Journal of the American Chemical Society (2019) | Abstract |
| Steven C. Hayden, Claire Chisholm, Rachael O. Grudt, Jeffery A. Aguiar, William M. Mook, Paul G. Kotula, Tatiana S. Pilyugina, Daniel C. Bufford, Khalid Hattar, Timothy J. Kucharski, Ihsan M. Taie, Michele L. Ostraat and Katherine L. Jungjohann. “Localized corrosion of low-carbon steel at the nanoscale,” npj Materials Degradation (2019) | Abstract |
| Alejandra Londono-Calderon, Srikanth Nayak, Curtis L. Mosher, Surya K. Mallapragada, and Tanya Prozorov. “New Approach to Electron Microscopy Imaging of Gel Nanocomposites in situ,” Micron (2019) | Abstract |
| Chang Li, Che Chen Tho, Daria Galaktionova, Xin Chen, Petr Král and Utkur Mirsaidov. ” Dynamics of amphiphilic block copolymers in an aqueous solution: direct imaging of micelle formation and nanoparticle encapsulation,” Nanoscale (2019) | Abstract |
| Xuezeng Tian, Utkarsh Anand, Utkur Mirsaidov and Haimei Zheng. “Spontaneous Reshaping and Splitting of AgCl Nanocrystals under Electron Beam Illumination,” Small (2018) | Abstract |
| Eli Sutter, Bo Zhang, Stephan Sutter and Peter Sutter. “In situ electron microscopy of the self-assembly of single-stranded DNA-functionalized Au nanoparticles in aqueous solution,” Nanoscale (2018) | Abstract |
| Biao Jin, Maria L. Sushko, Zhaoming Liu, Chuanhong Jin, and Ruikang Tang. “In Situ Liquid Cell TEM Reveals Bridge-Induced Contact and Fusion of Au Nanocrystals in Aqueous Solution,” Nano Letters (2018) | Abstract |
| Katherine L. Jungjohann, David R. Wheeler, Ronen Polsky, Susan M. Brozik, James A. Brozik, and Angela R.Rudolph. “Liquid-Cell Scanning Transmission Electron Microscopy and Fluorescence Correlation Spectroscopy of DNA-Directed Gold Nanoparticle Assemblies,” Micron (2018) | Abstract |
| Shu Fen Tan, Geeta Bisht, Utkarsh Anand, Michel Bosman, Xin Ee Yong, and Utkur Mirsaidov. “In situ Kinetic and Thermodynamic Growth Control of Au-Pd Core-Shell Nanoparticles.” Journal of the American Chemical Society (2018) | Abstract |
| Nikhilendra Singh, Timothy S. Arthur, Oscar Tutusaus, Jing Li, Kim Kisslinger, Huolin L. Xin, Eric A. Stach, Xudong Fan, and Rana Mohtadi. “Achieving High Cycling Rates via In-situ Generation of Active Nanocomposite Metal Anodes.” ACS Applied Energy Materials (2018) | Abstract |
| Mei Sun, Xing Li, Zhiqiang Tang, Xianlong Wei and Qing Chen. “Constant-Rate Dissolution of InAs Nanowires in Radiolytic Water Observed by In situ Liquid Cell TEM.” Nanoscale (2018) | Abstract |
| Peter Sutter, Bo Zhang and Eli Sutter. “Radiation damage during in situ electron microscopy of DNA-mediated nanoparticle assemblies in solution,” Nanoscale (2018) | Abstract |
| Feng Yan, Lili Liu, Tiffany R. Walsh, Yu Gong, Patrick Z. El-Khoury, Yanyan Zhang, Zihua Zhu, James J. De Yoreo, Mark H. Engelhard, Xin Zhang and Chun-Long Chen. “Controlled synthesis of highly-branched plasmonic gold nanoparticles through peptoid engineering,” Nature Communications (2018) | Abstract |
| Claudia Stauch, Christopher Hobbs, Aleksey Shmeliov, Valeria Nicolosi, Thomas Ballweg, Robert Luxenhofer, and Karl Mandel. “Colloidal Core–Satellite Supraparticles via Preprogramed Burst of Nanostructured Micro‐Raspberry Particles,” Particle & Particle Systems Characterization (2018) | Abstract |
| Khim Karki, Tyler Mefford, Daan Hein Alsem, Norman Salmon and William C. Chueh. “Replicating Bulk Electrochemistry in Liquid Cell Microscopy.” Microscopy & Microanalysis (2018) | Abstract |
| Jeung Hun Park, Tommy Watanabe, Ainsley Pinkowitz, David J. Duquette, Robert Hull, Daniel A. Steingart and Frances M. Ross. “In situ EC-TEM Studies of Metal Thin Film Corrosion in Liquid Solutions at Elevated Temperatures.” Microscopy & Microanalysis (2018) | Abstract |
| Alejandra Londono-Calderon, Lee Bendickson, Pierre E. Palo, Marit Nilsen-Hamilton, Surya Mallapragada and Tanya Prozorov. “In-Situ Nucleation, Growth and Evolution of Au Nanoparticles during Metallization of DNA Origami Visualized with HAADF-STEM.” Microscopy & Microanalysis (2018) | Abstract |
| Jared J. Lodico, William A. Hubbard and B. C. Regan. “Scanning TEM Electron Beam Induced Current Imaging in Water.” Microscopy & Microanalysis (2018) | Abstract |
| Shu Fen Tan, Sanoj Raj, Geeta Bisht, Harshini V. Annadata, Christian A. Nijhuis, Petr Král, and Utkur Mirsaidov. “Nanoparticle Interactions Guided by Shape‐Dependent Hydrophobic Forces,” Advanced Materials (2018) | Abstract |
| Chen Houa, Jiuhui Hanb, Pan Liua, Chuchu Yangb, Gang Huangb, Takeshi Fujitab, Akihiko Hiratab, and Mingwei Chen. “Operando observations of RuO2 catalyzed Li2O2 formation and decomposition in a Li-O2 micro-battery,” Nano Energy (2018) | Abstract |
| Pan Liu, Jiuhui Han, Xianwei Guo, Yoshikazu Ito, Chuchu Yang, Shoucong Ning, Takeshi Fujita, Akihiko Hirata and Mingwei Chen. “Operando characterization of cathodic reactions in a liquid-state lithium-oxygen micro-battery by scanning transmission electron microscopy,” Scientific Reports (2018) | Abstract |
| Jeung Hun Park, Nicholas M. Schneider, Daniel A. Steingart, Hariklia Deligianni, Suneel Kodambaka, and Frances M. Ross. “Control of Growth Front Evolution by Bi Additives during ZnAu Electrodeposition,” Nano Letters (2018) | Abstract |
| Trevor H. Moser, Hardeep Mehta, Chiwoo Park, Ryan T. Kelly, Tolou Shokuhfar, and James E. Evans. “The role of electron irradiation history in liquid cell transmission electron microscopy,” Science Advances (2018) | Abstract |
| Dongdong Xiao, Zhigang Wu, Miao Song, Jaehun Chun, Gregory K. Schenter, and Dongsheng Li. “Silver Nanocube and Nanobar Growth via Anisotropic Monomer Addition and Particle Attachment Processes,” Langmuir (2017) | Abstract |
| Lili Liu, Shuai zhang, Mark E. Bowden, Jharna Chaudhuri, and James J. De Yoreo. “In-situ TEM and AFM investigation of morphological controls during the growth of single crystal BaWO4,” Crystal Growth & Design (2017) | Abstract |
| Edward R. White, Jared J. Lodico & B. C. Regan. “Intercalation events visualized in single microcrystals of graphite,” Nature Communications (2017) | Abstract |
| YuBo Wang, Shuai Wang, and Xing Lu. “In Situ Observation of the Growth of ZnO Nanostructures Using Liquid Cell Electron Microscopy,” The Journal of Physical Chemistry C (2017) | Abstract |
| Mingyuan Ge, Ming Lu, Yong Chu & Huolin Xin. “Anomalous Growth Rate of Ag Nanocrystals Revealed by in situ STEM,” Scientific Reports (2017) | Abstract |
| Lucas R. Parent, Evangelos Bakalis, Abelardo Ramírez-Hernández, Jacquelin K. Kammeyer, Chiwoo Park, Juan de Pablo, Francesco Zerbetto, Joseph P. Patterson, and Nathan C. Gianneschi.”Directly Observing Micelle Fusion and Growth in Solution by Liquid-Cell Transmission Electron Microscopy,” Journal of the American Chemical Society (2017) | Abstract |
| See Wee Chee, Shu Fen Tan, Zhaslan Baraissov, Michel Bosman & Utkur Mirsaidov. “Direct observation of the nanoscale Kirkendall effect during galvanic replacement reactions,” Nature Communications (2017) | Abstract |
| Tanya Prozorov, Trevor P. Almeida, András Kovács, and Rafal E. Dunin-Borkowski. ” Off-axis electron holography of bacterial cells and magnetic nanoparticles in liquid,” Journal of The Royal Society Interface (2017) | Abstract |
| Michele Conroy, Jennifer A. Soltis, Rick S. Wittman, Frances N. Smith, Sayandev Chatterjee, Xin Zhang, Eugene S. Ilton, and Edgar C. Buck. “Importance of interlayer H bonding structure to the stability of layered minerals,” Scientific Reports (2017) | Abstract |
| Chuchu Yang, Jiuhui Han, Pan Liu, Chen Hou, Gang Huang, Takeshi Fujita, Akihiko Hirata, and Mingwei Chen. “Direct Observations of the Formation and Redox-Mediator-Assisted Decomposition of Li2O2 in a Liquid-Cell Li–O2 Microbattery by Scanning Transmission Electron Microscopy,” Advanced Materials (2017) | Abstract |
| Timothy S. Arthur, Per-Anders Glans, Nikhilendra Singh, Oscar Tutusaus, Kaiqi Nie, Yi-Sheng Liu, Fuminori Mizuno, Jinghua Guo, Daan Hein Alsem, Norman J. Salmon, and Rana Mohtadi. “Interfacial insight from operando sXAS/TEM for magnesium metal deposition with borohydride electrolytes,” Chemistry of Materials (2017) | Abstract |
| Jeung Hun Park, Daniel A. Steingart, Suneel Kodambaka, and Frances M. Ross. “Electrochemical electron beam lithography: Write, read, and erase metallic nanocrystals on demand,” Science Advances (2017) | Abstract |
| J. R. Vance and S. J. Dillon. “Thermally driven bubble evolution at a heater wire in water characterized by high-speed transmission electron microscopy,” Chemical Communications (2017) | Abstract |
| Juyeong Kim, Zihao Ou, Matthew R. Jones, Xiaohui Song and Qian Chen. “Imaging the polymerization of multivalent nanoparticles in solution,” Nature Communications (2017) | Abstract |
| Jianbo Wu, Wenpei Gao, Hong Yang, and Jian-Min Zuo. “Dissolution Kinetics of Oxidative Etching of Cubic and Icosahedral Platinum Nanoparticles Revealed by in Situ Liquid Transmission Electron Microscopy,” ACS Nano (2017) | Abstract |
| E. Sutter, P. Sutter, A. V. Tkachenko, R. Krahne, J. De Graff, M. Arciniegas and L. Manna. “In situ microscopy of the self-assembly of branched nanocrystals in solution,” Nature Communications (2016) | Abstract |
| Arjan P. H. Gelissen, Alex Oppermann, Tobias Caumanns, Pascal Hebbeker, Sarah K. Turnhoff, Rahul Tiwari, Sabine Eisold, Ulrich Simon, Yan Lu, Joachim Mayer, Walter Richtering, Andreas Walther, and Dominik Wöll.”3D Structures of Responsive Nanocompartmentalized Microgels,” Nano Letters (2016) | Abstract |
| J. P. Patterson, L. R. Parent, J. Cantlona, H. Eickhoffa, G. Bareda, J. E. Evansa and N.C. Gianneschia. “Picoliter Drop-On-Demand Dispensing for Multiplex Liquid Cell Transmission Electron Microscopy,” Microscopy and Microanalysis, Online (2016) | Abstract |
| Omid Sadeghi, Clément Falaise, Pedro I. Molina, Ryan Hufschmid, Charles F. Campana, Bruce C. Noll, Nigel D. Browning, and May Nyman. “Chemical Stabilization and Electrochemical Destabilization of the Iron Keggin Ion in Water,” Inorganic Chemistry (2016) | Abstract |
| R. R. Unocic, L. Baggetto, G. M. Veith, J. A. Aguiar, K. A. Unocic, R. L. Sacci, N. J. Dudneyb and K. L. Morea. “Probing battery chemistry with liquid cell electron energy loss spectroscopy,” Chem. Commun. Advance Article (2015) | Abstract |
| E. Firlar, S. Çınar, S. Kashyap, M. Akinc & T. Prozorov. “Direct Visualization of the Hydration Layer on Alumina Nanoparticles with the Fluid Cell STEM in situ,” Scientific Reports (2015) | Abstract |
| T. J. Woehl and T. Prozorov. “The Mechanisms for Nanoparticle Surface Diffusion and Chain Self-Assembly Determined from Real-Time Nanoscale Kinetics in Liquid,” The Journal of Physical Chemistry 119 (36), 21261-21269 (2015) | Abstract |
| J.H. Park, N.M. Schneider, J.M. Grogan, M.C. Reuter, H.H. Bau, S. Kodambaka & F.M. Ross. “Control of Electron Beam-Induced Au Nanocrystal Growth Kinetics through Solution Chemistry,” Nano Letters (2015) | Abstract |
| R.R. Unocic. “In-situ Liquid S/TEM: Practical Aspects, Challenges, and Opportunities,” Microscopy and Microanalysis (2015) | Abstract |
| W. Zhang, D.H. Alsem, F. Wang, N. Salmon. “In-Situ Liquid Cell TEM Studies of Electrochemical Reaction in Lithium-Ion Batteries,” Microscopy and Microanalysis (2015) | Abstract |
| J.P. Patterson, P. Abellan, M.S. Denny, C. Park, N.D. Browning, S.M. Cohen, J.E. Evans, N.C. Gianneschi. “Observing the Self-assembly of Metal-Organic Frameworks by In-Situ Liquid Cell TEM,” Microscopy and Microanalysis (2015) | Abstract |
| J.-M. Zuo, A. Yoon, W. Gao, J. Wu, H. Park. “Materials processes observed using dynamical environmental TEM at University of Illinois,” Microscopy and Microanalysis (2015) | Abstract |
| T.J. Woehal, S. Kashyap, E. Firlar, T. Perez-Gonzalez, D. Faivre, D. Trubitsyn, D. Bazylinski, T. Prozorov. “Correlative Electron and Fluorescence Microscopy of Magnetotactic Bacteria in Liquid: Toward In-Vivo Imaging,” Microscopy and Microanalysis (2015) | Abstract |
| T.J. Woehl, T. Prozorov. “Visualization of gold nanoparticle self-assembly kinetics,” Microscopy and Microanalysis (2015) | Abstract |
| N. Bhattarai, T. Prozorov. “In-situ STEM Investigation of Shape-Controlled Synthesis of Au-Pd Core-Shell Nanocube,” Microscopy and Microanalysis (2015) | Abstract |
| S.W. Chee, D. Loh, U Mirsaidov, P. Matsudaira, “Probing Nanoparticle Dynamics in 200 nm Thick Liquid Layers at Millisecond Time Resolution.” Microscopy & Microanalysis (2015) | Abstract |
| J.H. Park, N.M. Schneider, J.M. Grogan, M.C. Reuter, H.H. Bau, S. Kodambaka & F.M. Ross, “Control of Electron Beam-Induced Au Nanocrystal Growth Kinetics through Solution Chemistry.” Nano Letters (2015) |
Abstract |
| C. Wang. “In situ transmission electron microscopy and spectroscopy studies of rechargeable batteries under dynamic operating conditions: A retrospective and perspective view.” Journal of Materials Research, 30, (2015) pp 326-339 | Abstract |
| P. J. M. Smeets, K. R. Cho, R. G. E. Kempen, N. A. J. M. Sommerdijk, and J. J. De Yoreo. “Calcium carbonate nucleation driven by ion binding in a biomimetic matrix revealed by in situ electron microscopy”, Nature Materials Letters, Published Online 01/26/2015. | Abstract |
| E. Sutter, K. Jungjohann, S. Bliznakov, A. Courty, E. Maisonhaute, S. Tenney & P. Sutter. “In situ liquid-cell electron microscopy of silver–palladium galvanic replacement reactions on silver nanoparticles.” Nature Communications, 5, Article number: 4946 doi:10.1038/ncomms5946 | Abstract |
| M.H. Nielsen, S. Aloni, J.J. De Yoreo. “In situ TEM imaging of CaCO3 nucleation reveals coexistence of direct and indirect pathways”, Science vol. 345 iss. 6201 (2014) pp. 1158-1162 | Abstract |
| P. Abellan, B. L. Mehdi, L.R. Parent, M. Gu, C. Park, W. Xu, Y. Zhang, I. Arslan, J.G. Zhang, C.M. Wang, J.E. Evans, and N.D. Browning ” Probing the Degradation Mechanisms in Electrolyte Solutions for Li-Ion Batteries by in Situ Transmission Electron Microscopy” Nano Lett. 14:3 (2014) 1293-1299 |
Abstract |
| S.W. Chee, D.J. Duquette, F.M. Ross, and R. Hull. “Metastable Structures in Al Thin Films Before the Onset of Corrosion Pitting as Observed using Liquid Cell Transmission Electron Microscopy,” Micoscopy and Microanalysis 20:2 (2014) pp. 462‒468 | Abstract |
| R.R. Unocic, X.G. Sun, R.L. Sacci, L.A. Adamczyk, D.H. Alsem, S. Dai, N.J. Dudney, and K.L. More. “Direct Visualization of Solid Electrolyte Interphase Formation in Lithium-Ion Batteries with In Situ Electrochemical Transmission Electron Microscopy,” Microscopy and Microanalysis 20:4 (2014) pp.1029‒1037 | Abstract |
| R.L. Sacci, N. Dudney, K. More, L.R. Parent, I. Arslan, N.D. Browning, and R.R. Unocic. “Direct Visualization of Initial SEI Morphology and Growth Kinetics During Lithium Deposition by In-Situ Electrochemical Transmission Electron Microscopy,” Chem. Commun. 50 (2014) pp. 2104‒2107 | Abstract |
| J.M. Miller, D.H. Alsem, N. Salmon, N.E. Johnson and J.E. Hutchison. “Functionalized Surfaces to Improve Imaging Conditions in Liquid Cell Transmission Electron Microscopy. ” Microscopy and Microanalysis, 20:Suppl. 3 (2014), pp. 1140–1141 | Abstract |
| S. Kashyap, T.J. Woehl, X. Liu, S.K. Mallapragada, T. Prozorov. ”Nucleation of Iron Oxide Nanoparticles Mediated by Mms6 Protein In Situ“ ACS Nano (2014) In Print. | Abstract |
| M.T. Proetto, A.M. Rush, M.P. Chien, P.A. Baeza, J.P. Patterson, M.P. Thompson, N.H. Olson, C.E. Moore, A.L. Rheingold, C. Andolina, J. Millstone, S.B. Howell, N.D. Browning, J.E. Evans, and N.C. Gianneschi. “Dynamics of Soft Nanomaterials Captured by Transmission Electron Microscopy in Liquid Water,” J.A.C.S. 136:4 (2014) pp. 1162‒1165 | Abstract |
| L.R. Parent, D.B. Robinson, P.J. Cappillino, R.J. Hartnett, P. Abellan, J.E. Evans, N.D Browning, and I. Arslan. “In-Situ Observation of Directed Nanoparticle Aggregation During the Synthesis of Ordered Nanoporous Metal in Soft Templates,” Chemistry of Materials 26:3 (2014) pp. 1426‒1433 | Abstract |
| T.J. Woehl, C. Park, J.E. Evans, I. Arslan, W.D. Ristenpart, N.D. Browning. “Direct Observation of Aggregative Nanoparticle Growth: Kinetic Modeling of the Size Distribution and Growth Rate,” Nano Lett. 14 (2014) pp. 373‒378 | Abstract |
| T.J. Woehl, S. Kashyap, E. Firlar, T. Perez-Gonzalez, D. Faivre, D. Trubitsyn, D.A. Bazylinski and T. Prozorov. “Correlative Electron and Fluorescence Microscopy of Magnetotactic Bacteria in Liquid: Toward In Vivo Imaging” Scientific Reports 4, 6854 (2014) | Abstract |
| D.A. Fischer, D.H. Alsem, B. Simon, T. Prozorov and N. Salmon. “Development of an Integrated Platform for Cross-Correlative Imaging of Biological Specimens in Liquid using Light and Electron Microscopies.” Microscopy and Microanalysis, 19 (Suppl. 2) , pp 476-477. (2013) | Abstract |
| M. Gu, L.R. Parent, B.L. Mehdi, R.R. Unocic, M.T. McDowell, R.L. Sacci, W. Xu, J.G. Connell, P. Xu, P. Abellan, X. Chen,Y. Zhang, D.E. Perea, J.E. Evans, L.J. Lauhon, J.G. Zhang, J. Liu, N.D. Browning, Y. Cui, I. Arslan, and C.M. Wang. “Demonstration of an Electrochemical Liquid Cell for Operando Transmission Electron Microscopy Observation of the Lithiation/Delithiation Behavior of Si Nanowire Battery Anodes.” Nano Lett. 13:12 (2013) pp. 6106‒6112 | Abstract |
| S.W. Chee, F.M. Ross, D. Duquette, and R. Hull. “Studies of Corrosion of Al Thin Films using Liquid-Cell Transmission Electron Microscopy,” MRS Proceedings 1525 (2013) | Abstract |
| F.A. Plamper, A.P. Gelissen, J. Timper, A. Wolf, A.B. Zezin, W. Richtering, H. Tenhu, U. Simon, J. Mayer, O. V. Borisov, D.V. Pergushov. “Spontaneous Assembly of Miktoarm Stars into Vesicular Interpolyelectrolyte Complexes,” Macromol. Rapid Commun. 34 (2013) pp. 855–860 | Abstract |
| Zhu, Y. Jiang, W. Huang, H. Zhang, F. Lin, C. Jin. “Atomic Resolution Liquid-Cell Transmission Electron Microscopy Investigations of the Dynamics of Nanoparticles in Ultrathin Liquids,”Chem. Commun. 49 (2013) pp. 10944‒10946 | Abstract |
| K.L. Jungjohann, S. Bliznakov, P.W. Sutter, E.A. Stach, E.A. Sutter. “In-Situ Liquid Cell Electron Microscopy of the Solution Growth of Au-Pd Core-Shell Nanostructures,” Nano. Lett. 13 (2013) pp. 2964–2970 | Abstract |
| Y.Z. Liu, X.M. Lin, Y.G. Sun, T. Rajh. “In-Situ Visualization of Self-Assembly of Charged Gold Nanoparticles.” J. Am. Chem. Soc. 135:10 (2013) pp. 3764–3767 | Abstract |
| G. Zhu, Y. Jiang, W. Huang, H. Zhang, F. Lin, and C. Jin. “Atomic Resolution Liquid-Cell Transmission Electron Microscopy Investigations of the Dynamics of Nanoparticles in Ultrathin Liquids,” Chem. Commun. 49 (2013) pp. 10944‒10946 | Abstract |
| M.H. Nielsen, J.R.I. Lee, Q. Hu, T. Y.-J. Han, and J.J. De Yoreo, “Structural evolution, formation pathways and energetic controls during template-directed nucleation of CaCO3,” Faraday Discuss. 159 (2012) pp. 105–121 | Abstract |
| D. Li, M.H. Nielsen, J.R.I. Lee, C. Frandsen, J.F. Banfield, and J.J. De Yoreo. “Direction-Specific Interactions Control Crystal Growth by Oriented Attachment,” Science 336:6084 (2012) pp. 1014–1018 | Abstract |
| E.R. White, M. Mecklenburg, B. Shevitski, S.B. Singer, and B.C. Regan, “Charged nanoparticle dynamics in water induced by scanning transmission electron microscopy,” Langmuir 28:8 (2012) pp. 3695–3698 | Abstract |
| E.R. White, S.B. Singer, V. Augustyn, W.A. Hubbard, M. Mecklenburg, B. Dunn, and B.C. Regan,“In-Situ Transmission Electron Microscopy of Lead Dendrites and Lead Ions in Aqueous Solution” ACS Nano 6:7 (2012) pp. 6038–6317 | Abstract |
| K.L. Jungjohann, J.E. Evans, J.A Aguiar , I. Arslan, N.D. Browning. “Atomic-scale imaging and spectroscopy for in-situ liquid scanning transmission electron microscopy.” Microscopy & Microanalysis 18:03 (2012) pp. 621–627 | Abstract |
| L.R. Parent, D.B. Robinson, T.J. Woehl, W.D. Ristenpart, J.E. Evans, N.D. Browning, I. Arslan “Direct in-situ observation of nanoparticle synthesis in a liquid crystal surfactant template,” ACS Nano 6:4 (2012) pp. 3589–3596 | Abstract |
| T.J. Woehl , J. E. Evans, I. Arslan, W.D. Ristenpart , N.D. Browning “Direct in-situ determination of the mechanisms controlling nanoparticle nucleation and growth,” ACS Nano 6:10 (2012) pp. 8599–8610 | Abstract |
| J.E. Evans, K.L. Jungjohann, P.C.K. Wong, P.L. Chiua, G.H. Dutrowa, I. Arslan, N.D. Browning. “Visualizing macromolecular complexes with in-situ liquid scanning transmission electron microscopy” Micron 43:11 (2012) pp. 1085–1090 | Abstract |
| R.R. Unocic, L. Baggetto, K.A. Unocic, G.M. Veith, N.J. Dudney, and K.L. More. “Coupling EELS/EFTEM Imaging with Environmental Fluid Cell Microscopy.” Microscopy and Microanalysis 18 (Suppl 2), (2012) 1104-1105 | Abstract |
| K.L. Jungjohann, J.E. Evans, J.A Aguiar , I. Arslan, N.D. Browning. “Atomic-scale imaging and spectroscopy for in-situ liquid scanning transmission electron microscopy.” Microscopy & Microanalysis 18:03 (2012) pp. 621–627. | Abstract |
| K.L. Jungjohann, J.E. Evans, I. Arslan, N.D. Browning. “Electron Energy Loss Spectroscopy for Aqueous in-Situ Scanning Transmission Electron Microscopy.” Microscopy & Microanaysis 17:S2 (2011) pp. 778–779. | Abstract |
| J.E. Evans, K.L. Jungjohann, N.D. Browning and I. Arslan. “Controlled Growth of Nanoparticles from Solution with In-Situ Liquid Transmission Electron Microscopy,” Nano Lett. 11:7 (2011) pp. 2809–2813 | Abstract |
| N. de Jonge, D.B. Peckys, G.J. Kremers, D.W. Piston. “Electron microscopy of whole cells in liquid with nanometer resolution,” PNAS 106:7 (2009) pp. 2159–2164 | Abstract |
| J.E. Evans, N.D. Browning, “Enabling Direct Nanoscale Observations of Biological Reactions with Dynamic TEM,” Microscopy 62:1 (2013) pp. 147–156 | Abstract |
| E.R. White, M. Mecklenburg, B. Shevitski, S.B. Singer, and B.C. Regan, “Charged nanoparticle dynamics in water induced by scanning transmission electron microscopy,” Langmuir 28:8 (2012) pp. 3695–3698 | Abstract |
| R.R. Unocic, L.A. Adamczyk, N.J. Dudney, D.H. Alsem, N.J. Salmon, and K.L. More. “In-Situ Electron Microscopy of Electrical Energy Storage Materials,” ECS Fall Meeting 2010 | Abstract |
| C.M. Wang, W. Xu, J. Liu, D.W. Choi, B. Arey, L.V. Saraf, J.G. Zhang, Z.G. Yang, S. Thevuthasan, D.R. Baer, and N. Salmon. “In-situ transmission electron microscopy and spectroscopy studies of interfaces in Li ion batteries: Challenges and opportunities,” J. Mater. Res. 25:8 (2010) pp. 1541–1547 | Abstract |
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