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バルク液中電気化学用ホルダー
![](https://hummingbirdscientific.co.jp/wp-content/uploads/gen-V-liquid-side-view-e1564676537972.png)
1490 series | |
Total Electrodes | 6 |
True Reference Electrode | Yes- drift rate less than 0.1 mV/min |
True Counter Electrode | Yes |
Counter Electrode Material | User’s choice of material |
Electrolytes | Aqueous, Wide range of organics* |
Spacer range | 100nm to 2 um* |
Heating Capability | Yes |
EELS/ EDS Compatible | Yes |
TEM Compatibility | TFS/FEI, JEOL, Hitachi |
バルク電気化学実験をその場で再現
第5世代バルク液中電気化学用ホルダーにより、透過型電子顕微鏡内で、初めて、バルクと同等なレベルの電気化学環境を完全に再現することができるようになりました 。さらに 、新規に開発されたハードウェアシステムにより、バルク同様のサイクルを有する完全な電気化学プロセスを、定量的に測定することが可能になりました。
モデル化合物であるCuSO4溶液のサイクリックボルタンメトリー(CV)測定を行い、活性電極からの銅のメッキと剥離を観察した結果を動画として紹介します。銅のメッキと剥離は作用電極で起こっており、実際のバルクの挙動を示しています。
当社の新しい液中用チップセルにより、世界で初めてTEMによるバルクレベルのデータを再現することが可 能 になりました。
Video Right: その場液中セルによる銅メッキと CuSO4 溶液からの剥離。画像の黄色い点は、対応するCVカーブの位置を示しています。
ペンシルバニア大学のRui Filipe Serra Maia博士およびEric Stach博士と共同で取得した社内データです。
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Electrochemical deposition of a conducting polymer on a gold electrode
Video on the left shows the methodological and controlled deposition of polyaniline – a conducting polymer – from solution into a gold electrode. The deposition starts at the interface between the working electrode and electrolyte solution. The electrode surface is heavily modified as the polymer deposits. This observation helps understanding the rate determining processes of nucleation and growth, which has an important application in corrosion protection of materials.
Hummingbird Scientific internal data.
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Khim Karki, Rui Serra-Maia, Eric Stach, Daan Hein Alsem, Norman Salmon. “Realistic Bulk Electrochemistry in Liquid Cell Microscopy.” Microscopy & Microanalysis (2020) | Abstract |
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Khim Karki, Tyler Mefford, Daan Hein Alsem, Norman Salmon, and William C. Chueh. “Replicating Bulk Electrochemistry in Liquid Cell Microscopy,” Microscopy & Microanalysis (2018) | Abstract |
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Jeung Hun Park, Tommy Watanabe, Ainsley Pinkowitz, David J. Duquette, Robert Hull, Daniel A. Steingart and Frances M. Ross. “In situ EC-TEM Studies of Metal Thin Film Corrosion in Liquid Solutions at Elevated Temperatures.” Microscopy & Microanalysis (2018) | Abstract |
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Chen Houa, Jiuhui Hanb, Pan Liua, Chuchu Yangb, Gang Huangb, Takeshi Fujitab, Akihiko Hiratab, and Mingwei Chen. “Operando observations of RuO2 catalyzed Li2O2 formation and decomposition in a Li-O2 micro-battery,” Nano Energy (2018) | Abstract |
Pan Liu, Jiuhui Han, Xianwei Guo, Yoshikazu Ito, Chuchu Yang, Shoucong Ning, Takeshi Fujita, Akihiko Hirata and Mingwei Chen. “Operando characterization of cathodic reactions in a liquid-state lithium-oxygen micro-battery by scanning transmission electron microscopy,” Scientific Reports (2018) | Abstract |
Jeung Hun Park, Nicholas M. Schneider, Daniel A. Steingart, Hariklia Deligianni, Suneel Kodambaka, and Frances M. Ross. “Control of Growth Front Evolution by Bi Additives during ZnAu Electrodeposition,” Nano Letters (2018) | Abstract |
Trevor H. Moser, Hardeep Mehta, Chiwoo Park, Ryan T. Kelly, Tolou Shokuhfar, and James E. Evans. “The role of electron irradiation history in liquid cell transmission electron microscopy,” Science Advances (2018) | Abstract |
Lili Liu, Shuai zhang, Mark E. Bowden, Jharna Chaudhuri, and James J. De Yoreo. “In-situ TEM and AFM investigation of morphological controls during the growth of single crystal BaWO4,” Crystal Growth & Design (2017) | Abstract |
Edward R. White, Jared J. Lodico & B. C. Regan. “Intercalation events visualized in single microcrystals of graphite,” Nature Communications (2017) | Abstract |
YuBo Wang, Shuai Wang, and Xing Lu. “In Situ Observation of the Growth of ZnO Nanostructures Using Liquid Cell Electron Microscopy,” The Journal of Physical Chemistry C (2017) | Abstract |
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Chuchu Yang, Jiuhui Han, Pan Liu, Chen Hou, Gang Huang, Takeshi Fujita, Akihiko Hirata, and Mingwei Chen. “Direct Observations of the Formation and Redox-Mediator-Assisted Decomposition of Li2O2 in a Liquid-Cell Li–O2 Microbattery by Scanning Transmission Electron Microscopy,” Advanced Materials (2017) | Abstract |
. Jongwoo Lim, Yiyang Li, Daan Hein Alsem, Hongyun So, Sang Chul Lee, Peng Bai, Daniel A. Cogswell, Xuxhao Liu, Norman Jin, Young-sang Yu, Norman J. Salom, David A. Shapiro, Martin Z. Bazant, Tolek Tyliszczak, and William C. Chueh. “Origin and hysteresis of lithium compositional spatiodynamics within battery primary particles,” Science (2017) | Abstract |
Eli Fahrenkrug, Daan Hein Alsem, Norman Salmon, and Stephen Maldonado. “Electrochemical Measurements in In Situ TEM Experiments,” Journal of the Electrochemical Society (2017) | Abstract |
Timothy S. Arthur, Per-Anders Glans, Nikhilendra Singh, Oscar Tutusaus, Kaiqi Nie, Yi-Sheng Liu, Fuminori Mizuno, Jinghua Guo, Daan Hein Alsem, Norman J. Salmon, and Rana Mohtadi. “Interfacial insight from operando sXAS/TEM for magnesium metal deposition with borohydride electrolytes,” Chemistry of Materials (2017) | Abstract |
Jeung Hun Park, Daniel A. Steingart, Suneel Kodambaka, and Frances M. Ross. “Electrochemical electron beam lithography: Write, read, and erase metallic nanocrystals on demand,” Science Advances (2017) | Abstract |
Jianbo Wu, Wenpei Gao, Hong Yang, and Jian-Min Zuo. “Dissolution Kinetics of Oxidative Etching of Cubic and Icosahedral Platinum Nanoparticles Revealed by in Situ Liquid Transmission Electron Microscopy,” ACS Nano (2017) | Abstract |
Omid Sadeghi, Clément Falaise, Pedro I. Molina, Ryan Hufschmid, Charles F. Campana, Bruce C. Noll, Nigel D. Browning, and May Nyman. “Chemical Stabilization and Electrochemical Destabilization of the Iron Keggin Ion in Water,” Inorganic Chemistry (2016) | Abstract |
R. R. Unocic, L. Baggetto, G. M. Veith, J. A. Aguiar, K. A. Unocic, R. L. Sacci, N. J. Dudneyb and K. L. Morea. “Probing battery chemistry with liquid cell electron energy loss spectroscopy,” Chem. Commun. Advance Article (2015) | Abstract |
R.R. Unocic. “In-situ Liquid S/TEM: Practical Aspects, Challenges, and Opportunities,” Microscopy and Microanalysis (2015) | Abstract |
W. Zhang, D.H. Alsem, F. Wang, N. Salmon. “In-Situ Liquid Cell TEM Studies of Electrochemical Reaction in Lithium-Ion Batteries,” Microscopy and Microanalysis (2015) | Abstract |
J.P. Patterson, P. Abellan, M.S. Denny, C. Park, N.D. Browning, S.M. Cohen, J.E. Evans, N.C. Gianneschi. “Observing the Self-assembly of Metal-Organic Frameworks by In-Situ Liquid Cell TEM,” Microscopy and Microanalysis (2015) | Abstract |
J.-M. Zuo, A. Yoon, W. Gao, J. Wu, H. Park. “Materials processes observed using dynamical environmental TEM at University of Illinois,” Microscopy and Microanalysis (2015) | Abstract |
T.J. Woehal, S. Kashyap, E. Firlar, T. Perez-Gonzalez, D. Faivre, D. Trubitsyn, D. Bazylinski, T. Prozorov. “Correlative Electron and Fluorescence Microscopy of Magnetotactic Bacteria in Liquid: Toward In-Vivo Imaging,” Microscopy and Microanalysis (2015) | Abstract |
T.J. Woehl, T. Prozorov. “Visualization of gold nanoparticle self-assembly kinetics,” Microscopy and Microanalysis (2015) | Abstract |
N. Bhattarai, T. Prozorov. “In-situ STEM Investigation of Shape-Controlled Synthesis of Au-Pd Core-Shell Nanocube,” Microscopy and Microanalysis (2015) | Abstract |
S.W. Chee, D. Loh, U Mirsaidov, P. Matsudaira, “Probing Nanoparticle Dynamics in 200 nm Thick Liquid Layers at Millisecond Time Resolution.” Microscopy & Microanalysis (2015) | Abstract |
C. Wang. “In situ transmission electron microscopy and spectroscopy studies of rechargeable batteries under dynamic operating conditions: A retrospective and perspective view.” Journal of Materials Research, 30, (2015) pp 326-339 | Abstract |
P. J. M. Smeets, K. R. Cho, R. G. E. Kempen, N. A. J. M. Sommerdijk, and J. J. De Yoreo. “Calcium carbonate nucleation driven by ion binding in a biomimetic matrix revealed by in situ electron microscopy”, Nature Materials Letters, Published Online 01/26/2015. | Abstract |
E. Sutter, K. Jungjohann, S. Bliznakov, A. Courty, E. Maisonhaute, S. Tenney & P. Sutter. “In situ liquid-cell electron microscopy of silver–palladium galvanic replacement reactions on silver nanoparticles.” Nature Communications, 5, Article number: 4946 doi:10.1038/ncomms5946 | Abstract |
M.H. Nielsen, S. Aloni, J.J. De Yoreo. “In situ TEM imaging of CaCO3 nucleation reveals coexistence of direct and indirect pathways”, Science vol. 345 iss. 6201 (2014) pp. 1158-1162 | Abstract |
P. Abellan, B. L. Mehdi, L.R. Parent, M. Gu, C. Park, W. Xu, Y. Zhang, I. Arslan, J.G. Zhang, C.M. Wang, J.E. Evans, and N.D. Browning ” Probing the Degradation Mechanisms in Electrolyte Solutions for Li-Ion Batteries by in Situ Transmission Electron Microscopy” Nano Lett. 14:3 (2014) 1293-1299 |
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S.W. Chee, D.J. Duquette, F.M. Ross, and R. Hull. “Metastable Structures in Al Thin Films Before the Onset of Corrosion Pitting as Observed using Liquid Cell Transmission Electron Microscopy,” Micoscopy and Microanalysis 20:2 (2014) pp. 462‒468 | Abstract |
R.R. Unocic, X.G. Sun, R.L. Sacci, L.A. Adamczyk, D.H. Alsem, S. Dai, N.J. Dudney, and K.L. More. “Direct Visualization of Solid Electrolyte Interphase Formation in Lithium-Ion Batteries with In Situ Electrochemical Transmission Electron Microscopy,” Microscopy and Microanalysis 20:4 (2014) pp.1029‒1037 | Abstract |
R.L. Sacci, N. Dudney, K. More, L.R. Parent, I. Arslan, N.D. Browning, and R.R. Unocic. “Direct Visualization of Initial SEI Morphology and Growth Kinetics During Lithium Deposition by In-Situ Electrochemical Transmission Electron Microscopy,” Chem. Commun. 50 (2014) pp. 2104‒2107 | Abstract |
D.A. Fischer, D.H. Alsem, B. Simon, T. Prozorov and N. Salmon. “Development of an Integrated Platform for Cross-Correlative Imaging of Biological Specimens in Liquid using Light and Electron Microscopies.” Microscopy and Microanalysis, 19 (Suppl. 2) , pp 476-477. (2013) | Abstract |
M. Gu, L.R. Parent, B.L. Mehdi, R.R. Unocic, M.T. McDowell, R.L. Sacci, W. Xu, J.G. Connell, P. Xu, P. Abellan, X. Chen,Y. Zhang, D.E. Perea, J.E. Evans, L.J. Lauhon, J.G. Zhang, J. Liu, N.D. Browning, Y. Cui, I. Arslan, and C.M. Wang. “Demonstration of an Electrochemical Liquid Cell for Operando Transmission Electron Microscopy Observation of the Lithiation/Delithiation Behavior of Si Nanowire Battery Anodes.” Nano Lett. 13:12 (2013) pp. 6106‒6112 | Abstract |
S.W. Chee, F.M. Ross, D. Duquette, and R. Hull. “Studies of Corrosion of Al Thin Films using Liquid-Cell Transmission Electron Microscopy,” MRS Proceedings 1525 (2013) | Abstract |
K.L. Jungjohann, S. Bliznakov, P.W. Sutter, E.A. Stach, E.A. Sutter. “In-Situ Liquid Cell Electron Microscopy of the Solution Growth of Au-Pd Core-Shell Nanostructures,” Nano. Lett. 13 (2013) pp. 2964–2970 | Abstract |
Y.Z. Liu, X.M. Lin, Y.G. Sun, T. Rajh. “In-Situ Visualization of Self-Assembly of Charged Gold Nanoparticles.” J. Am. Chem. Soc. 135:10 (2013) pp. 3764–3767 | Abstract |
E.R. White, S.B. Singer, V. Augustyn, W.A. Hubbard, M. Mecklenburg, B. Dunn, and B.C. Regan,“In-Situ Transmission Electron Microscopy of Lead Dendrites and Lead Ions in Aqueous Solution” ACS Nano 6:7 (2012) pp. 6038–6317 | Abstract |
T.J. Woehl , J. E. Evans, I. Arslan, W.D. Ristenpart , N.D. Browning “Direct in-situ determination of the mechanisms controlling nanoparticle nucleation and growth,” ACS Nano 6:10 (2012) pp. 8599–8610 | Abstract |
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